Crystal structures of two erbium(III) complexes with 4-aminobenzoic acid and 4-chloro-3-nitrobenzoic acid

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Crystal structures of two erbium(III) complexes with 4-amino­benzoic acid and 4-chloro-3-nitro­benzoic acid

The crystal structures of two erbium(III) complexes with 4-amino-benzoic acid (4-ABAH), namely bis-(μ2-4-amino-benzoato-κ(2) O:O')bis-[bis(4-amino-benzoato-κ(2) O,O')di-aqua-erbium(III)] dihydrate, [Er2(C7H6NO2)6(H2O)4]·2H2O, (I), and 4-chloro-3-nitro-benzoic acid (CLNBAH), namely poly[hexa-kis-(μ2-4-chloro-3-nitro-benzoato-κ(2) O:O')bis-(dimethyl sulfoxide-κO)dierbium(III)], [Er2(C7H3ClNO4)6(C...

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In the title compound, C(10)H(9)ClN(2)O(5), the nitro group is significantly twisted out of the plane of the benzene ring to which it is attached [dihedral angle = 27.4 (6)°]. In the crystal, mol-ecules are linked into centrosymmetric dimers via pairs of O-H⋯O hydrogen bonds. These dimers are further linked by N-H⋯O hydrogen bonds into double chains running along the a axis.

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N-(4-Chloro-3-nitro­phen­yl)maleamic acid

In the mol-ecule of the title compound, C(10)H(7)ClN(2)O(5), the acyclic C=C double bond is cis configured. The C=O and O-H bonds of the acid group are in a relatively rare anti position to each other, due to the donation of intramolecular hydrogen bond to the amide by the carboxyl group. The nitro group is significantly twisted [dihedral angle = 66.9 (3)°] out of the plane of the remaining ato...

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N-(3-Chloro-4-methyl­phen­yl)maleamic acid

In the title compound, C(11)H(10)ClNO(3), the dihedral angle between the benzene ring and the amide group is 6.6 (10)° and an intramolecular O-H⋯O hydrogen bond occurs. In the crystal, molecules are linked by N-H⋯O hydrogen bonds, generating C(7) zigzag chains.

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N-(4-Chloro-3-methyl­phen­yl)succinamic acid

The title compound, C(11)H(12)ClNO(3), crystallizes with two independent mol-ecules in the asymmetric unit in which the dihedral angles between the benzene ring and the amide group are 55.0 (2) and 28.2 (3)°. The two independent mol-ecules are linked by an N-H⋯O hydrogen bond. In the crystal, mol-ecules form inversion dimers via pairs of O-H⋯O hydrogen bonds. These dimers are linked into sheets...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Crystallographic Communications

سال: 2015

ISSN: 2056-9890

DOI: 10.1107/s2056989015020319